In recent months, research teams from both Canada and Italy have published comparative analyses of sustainable ammonia production pathways.
These projects aim to quantify the costs and benefits of combining Haber-Bosch with a renewable hydrogen feedstock. Both projects examine the carbon intensity of ammonia production but, while the Canadian study broadens its remit to a full life cycle analysis, including global warming potential, human toxicity, and abiotic depletion, the Italian study focuses primarily on energy efficiency.
The US Department of Energy (DOE) is currently supporting six fundamental research projects that will develop "novel catalysts and mechanisms for nitrogen activation," which it hopes will lead to future sustainable ammonia synthesis technologies.
These projects, announced in August 2016 and administered by the Office of Basic Energy Sciences, aim "to investigate some of the outstanding scientific questions in the synthesis of ammonia (NH3) from nitrogen (N2) using processes that do not generate greenhouse gases."
I recently wrote about a vast future market for merchant ammonia: transporting carbon-free energy from Australia's deserts to Japan's electricity grid.
Now, however, it is clear that Japan could face international competition for Australia's solar-ammonia resources. Jeff Connolly, CEO of Siemens Pacific, wrote last month about his ambitions for ammonia as an energy export commodity.
Last week, ARPA-E announced funding for eight technologies that aim to make ammonia from renewable electricity, air, and water.
The technological pathways being developed include adaptations of the Haber-Bosch process - seeking improvements in catalysts and absorbents - as well as novel electrochemical processes.
Each of these awards must produce an "end-of-project deliverable." For chemical processes, this will be a "bench scale reactor" that produces >1 kg of ammonia per day; and for electrochemical projects, it will be a "short stack prototype" capable of producing >100 g of ammonia per day.
A multi-billion dollar clean energy innovation fund was launched last year, at the Paris climate conference. Led by Bill Gates, the private funding enterprise aimed to develop "groundbreaking new carbon-neutral technologies," without specifying details.
Now, the Breakthrough Energy Coalition is starting work, and one of its initial Technical Quests is to make "Zero-GHG Ammonia Production" a reality.
Earlier this year, the US Department of Energy (DOE) hosted a day-long meeting "to explore the scientific challenges associated with discovering alternative, sustainable processes for ammonia production."
The report that came out of this roundtable discussion presents the participants' views on "the current state-of-the-art and the potential challenges and research opportunities ... for heterogeneous catalysis and homogeneous and enzyme catalysis."
I wrote last week about ARPA-E's "transformative" ammonia synthesis technologies, describing three technology pathways under development: low pressure Haber-Bosch, electrochemical processes, and advanced electrolysis.
ARPA-E's ambitious R&D program might imply that a meaningful, commercial market for sustainable ammonia is still decades away. It represents, however, only the slow American tip of a fast-moving global iceberg.
In Japan, where there's no debate about climate science, the national effort is already well underway, with three programs to develop low-carbon ammonia synthesis under the Cross-ministerial Strategic Innovation Promotion Program (SIP), 'Energy Carriers.'
The US Department of Energy's Advanced Research Project Agency (ARPA-E) is funding projects with a view to commercializing low- and zero-carbon ammonia synthesis technologies.
Grigorii Soloveichik, ARPA-E Program Director, described the aims and challenges of his agency's initiative and introduced the technologies currently in development in his keynote presentation at the recent NH3 Fuel Conference, in September 2016.
Agrium continues to plan for the potential restart of its ammonia-urea plant in Kenai, Alaska: its draft water permit is now entering a 30-day public comment period.
However, the fact sheet for the draft permit contains one particularly interesting chart, which follows below, to illustrate the water flows throughout the ammonia-urea plant. In an industry that holds its data close, this is a refreshingly detailed flow chart.
This website will remain a project tracker for ammonia capacity expansions.
However, it will also begin reporting on - and agitating for - the development and deployment of new, sustainable ammonia synthesis technologies.
I will feature projects from my (extensive) database of pre- and post-commercialization ammonia synthesis technologies, and demonstrate the commercial benefits of moving this mature industry beyond the acceptance of the technical limits of Haber-Bosch.
To start with, I'm presenting a conference paper next week to introduce "The Investment Case for Sustainable Ammonia Synthesis Technologies." My paper will be available online after the conference, and my abstract follows below.
You're welcome to check out next week's NH3 Fuel Conference, which is hosted by UCLA, in Los Angeles, on Monday 9/19 and Tuesday 9/20.
To make urea, fertilizer producers combine ammonia with carbon dioxide (CO2), but when farmers apply that urea to the soil, an equal amount of CO2 is emitted to the atmosphere. No CO2 is permanently stored or sequestered through the production of urea.
This is a statement of the obvious, I'm told, but it's worth stating for three reasons. First, not everyone knows it. Second, there was zero data in the academic literature supporting the fact, until now (see below). And third, next generation ammonia-urea plants with "zero-emissions" are becoming a reality, despite some of these new technologies relying on fossil fuel feedstocks.